Ore-forming material sources of the Jurassic Cu–Pb–Zn mineralization in the Qin–Hang ore belt,South China: Constraints from S–Pb isotopes     

《Chemie der Erde / Geochemistry》2019,79(2):280-306

The Qin–Hang ore belt in South China, which serves as the boundary between the Yangtze and Cathaysia blocks, is marked by extensive Jurassic porphyry-skarn-metasomatic Cu–Pb–Zn polymetallic mineralization. In this contribution, S and Pb isotopic compositions of the Baoshan Cu–Pb–Zn deposit in the western portion of the Qin–Hang ore belt were analyzed to determine the ore-forming material sources in the area. This is coupled by the first systematic collection, compilation and interpretation of previously published S and Pb isotopic data of multiple sulfide minerals to reveal the metal origin and accumulation mechanism of the Cu–Pb–Zn mineralization from the significant deposits in the region (i.e., Dexing, Qibaoshan, Shuikoushan, Baoshan, Huangshaping, Tongshanling and Dabaoshan). The results show that Cu mineralization is characterized by low and narrow δ³⁴S (‰) range of values (–5 to 6) and Pb isotopic ratios (²⁰⁸Pb/²⁰⁴Pb = 38.0–39.0, ²⁰⁷Pb/²⁰⁴Pb = 15.4–15.8, and ²⁰⁶Pb/²⁰⁴Pb = 17.7–18.7), which are consistent with those of local porphyries. In contrast, the Pb–Zn mineralization reveals higher and more variable δ³⁴S (‰) values (–4 to 18) and Pb isotopic ratios (²⁰⁸Pb/²⁰⁴Pb = 38.0–39.5, ²⁰⁷Pb/²⁰⁴Pb = 15.3–16.0, and ²⁰⁶Pb/²⁰⁴Pb = 18.0–19.0) that correspond to wall-rock and basement rock compositions in the region. This indicates that the sulfur and lead that formed the Cu mineralization in the Qin–Hang ore belt was mainly sourced from regional magmatism with mantle contributions, whereas the sulfur and lead for the Pb–Zn mineralization was likely derived from the host sedimentary rocks and Proterozoic metamorphic basement rocks, respectively. The S and Pb isotopic data, combined with the geochemical signatures of mineralization-related porphyries, suggest that the Cu was sourced from the deeper levels along with mantle-derived magmas. In contrast, the Pb–Zn probably originated from the crust, with partial melting of the crystalline basement in the Cathaysia Block. Consequently, a three-stage genetic model is proposed to explain the ore-forming processes of the Qin–Hang Cu-polymetallic belt in South China.  相似文献   

内蒙古莲花山铜矿床辉钼矿铼-锇年代学、矿石硫-铅同位素地球化学与矿床成因     

康欢  刘翼飞  江思宏 《地质学报》2019,93(12):3082-3094

莲花山铜矿床位于内蒙古大兴安岭中南段,其成因还存在一定的争议。本文对其开展了辉钼矿铼-锇测年和硫化物的硫、铅同位素研究。研究结果显示,矿床形成于139.1±1.1 Ma,属于早白垩世,并非前人所认为的三叠纪。莲花山铜矿床硫化物的硫同位素组成(δ~(34)S_(V-CDT))分布于-1.5‰至5.0‰之间,具有塔式分布特征,与大兴安岭中南段地区产出的其他锡-钨-银多金属矿床中硫化物的硫同位素组成非常类似,显示硫来源于深部岩浆,受到浅部硫源混染程度较小。莲花山铜矿床硫化物的铅同位素组成具有线性排列特征,显示成矿作用过程中成矿物质经历了两端元的混合,包括一个低放射性成因铅端元和一个高放射性成因铅端元。这种铅同位素特征与大兴安岭中南段产出的其他多金属矿床中的铅同位素具有非常相似的特征,反映了这些矿床可能含有一个相似的低放射性成因铅端元,但受到浅部不同铅的混染。莲花山铜矿床辉钼矿中铼的含量平均为1078×10~(-9),低于兴蒙造山带中与俯冲环境形成的斑岩铜矿床中辉钼矿铼的含量2个数量级,但与高分异花岗岩有关的锡-钨-银多金属矿床中辉钼矿中铼的含量相似,显示莲花山铜矿床的形成可能与高分异花岗质岩浆活动有关,是高分异花岗岩晚期岩浆-热液作用的结果。莲花山铜矿床的产出指示区域内可能具有寻找高分异花岗岩型深成高温锡-钨矿化的潜力。  相似文献   

浙东地区东园花岗岩体年代学、地球化学特征及其地质意义     

廖圣兵  陈荣  褚平利  曾剑威  张彦杰  王存智  黄文成 《大地构造与成矿学》2017,41(5)

浙东地区岩浆岩广泛分布,受区域构造控制较明显,总体沿北东向余姚-丽水断裂带分布。本文对东园花岗岩体开展了详细的年代学和岩石地球化学研究。东园岩体主要由二长花岗岩、石英二长岩和少量花岗岩组成,主岩体二长花岗岩的LA-ICP-MS锆石U-Pb年龄为235.6±0.7 Ma(MSWD=0.97,2σ),花岗岩为238.1±0.8 Ma(MSWD=1.3,2σ),均属中三叠世产物。二长花岗岩和石英二长岩为准铝质-弱过铝质的钙碱性花岗岩,具高硅(62.94%~75.29%)、富碱(Na_2O+K_2O=8.17%~9.34%)且富钾(K_2O=4.54%~5.63%)的特征,轻重稀土分馏明显,具有较强的Eu正异常(δEu=0.94~2.43),明显亏损高场强元素(HFSE)Nb、P、Ti,而相对富集Th、Hf,富集轻稀土元素(LREE)和大离子亲石元素(LILE)Rb,相对贫Ba。岩体属高(-中等)分异I型花岗岩,岩浆来源于具弧属性的加厚地壳部分熔融,形成于同碰撞向后碰撞阶段转变的大地构造环境,可能与太平洋板块向华南板块俯冲作用事件有关。  相似文献   

松潘造山带金川地区观音桥晚三叠世二云母花岗岩的成因及其地质意义     

朱毓  赖绍聪  秦江锋 《地质论评》2017,63(6):1465-1478

松潘造山带内发育大量印支期花岗岩,这些花岗岩类对于该地区岩浆活动、基底性质和构造演化的研究有着重要的意义。金川地区观音桥二云母花岗岩位于松潘造山带东部,属于晚三叠世花岗岩。岩石具有高硅(SiO_2=72.08%~73.95%)、富碱(K_2O=4.44%~5.84%、Na_2O=3.29%~3.93%)的特征,其A/CNK值为1.08~1.22,属于过铝质高钾钙碱性S型花岗岩类。岩石富集大离子亲石元素,亏损部分高场强元素,具有明显的Eu负异常(δEu=0.26~0.38)。观音桥二云母花岗岩的ε_(Nd)(t)=-7.9~-10.1(平均为-8.9)不高,Nd同位素二阶段模式年龄T_(2DM)值为1.42~1.57 Ga,显示源岩应该为中元古代地壳岩石。岩石高的Rb/Sr值和低的CaO/Na_2O值、较低的Al_2O_3/TiO_2值和低的Rb/Ba值,表明其起源于泥质源岩的部分熔融。综合地球化学、同位素特征和区域地质资料,笔者等认为金川地区观音桥二云母花岗岩是在松潘造山带挤压背景下,由中—上地壳泥质源岩发生部分熔融而形成。  相似文献   

Geochronological and geochemical characteristics of fractionated I-type granites associated with the skarn mineralization in the Sangan mining region,NE Iran     

《Ore Geology Reviews》2017

The Sangan mining region, which has a proven reserve of approximately 1000 Mt of 53% iron ore, is located in the Khaf-Kashmar-Bardeskan volcano-plutonic belt in northeastern Iran. The geological units in the eastern zone of the Sangan region consist of Precambrian schists, Jurassic sedimentary rocks and Tertiary subvolcanic granitoid intrusions. Iron skarn mineralization consists of stratiform and massive bodies in the carbonate rocks that are adjacent to the granitoid intrusions. Detailed field mapping revealed that 39-Ma syenitic intrusive bodies in the western and central zones of the Sangan region were the main sources of heat and fluid for the iron mineralization.A Mid-Cenozoic biotite granite pluton is associated with the eastern anomalies. However, field relationships suggested that this pluton is not the source of the metals, heat or fluids that were responsible for the iron mineralization. This pluton is rich in silica (SiO₂ contents from 66.4 to 79.1 wt%) and is characterized by high-K series with metaluminous to slightly peraluminous affinity.Geochronological (U-Pb zircon method) and geochemical data, including major and trace elements and Sr-Nd-Pb isotopes, define the complex origin of these plutons, which consist of alkaline granitoids that appear to be A-type in character but also show I-type affinity.New geochemical and isotopic data from plutons in the eastern anomalies and data from previous studies of the western and central anomalies and the southeastern intrusive rocks in the Sangan region show that these plutons have close affiliation with lower to upper crust-derived melts and were largely modified into highly fractionated I-type granite. These rocks were derived from and emplaced by varying degrees of partial melting during the Middle Eocene (Bartonian to Lutetian, 38.3–43.9 Ma) from a crustal protolith in a normal to mature volcanic continental arc setting.The Sangan granitoids were produced from crustal assimilation by a heat source from mantle melts, which are associated with the Kashmar-Neotethyan slab that subducted under Eurasia. The Khaf-Kashmar-Bardeskan igneous rocks reflect an active Cenozoic plate margin that was related to the closure of the Kashmar-Neotethyan Sea between the Lut and Eurasia blocks because of the continuous convergence between the Arabian and Iran plates during the Late Cretaceous–Early Paleocene.  相似文献   

A crustal source for ca. 165 Ma post-collisional granites related to mineralization in the Jianglang dome of the Songpan-Ganzi Orogen,eastern Tiebtan Plateau     

《Chemie der Erde / Geochemistry》2017,77(4):573-586

The Wenjiaping and Wulaxi granite plutons are located in the Jianglang dome, which is a key domain for providing deep insight into the tectonic evolution of the Songpan-Ganzi Orogen. Two granites are composed chiefly of K-feldspar, quartz, biotite with minor plagioclase and hornblende. This study presents zircon U-Pb chronology, geochemistry and Hf isotope data to explore their petrogenesis and metallogenic implications. Zircon U-Pb dating provides crystallization ages of 164.5 ± 0.9 Ma and 163.4 ± 0.9 Ma for the Wenjiaping granite, and 164.3 ± 1.7 Ma for the Wulaxi granite. This indicates that they were formed synchronously. They also contain inherited zircons related to the Rodinia and Gondwana supercontinents and the Emeishan large igneous province. Their mineral assemblages lack peraluminous (e.g., garnet and cordierite) and high-temperature (e.g., pyroxene and fayalite) minerals. They are characterized by low A/CNK (1.10–0.99), FeO^T/MgO (8.55–2.83) and K₂O/N₂O ratios (1.34–0.51) with low Zr + Nb + Ce + Y concentrations (average 258 ppm) and zircon saturation temperatures (781–651 °C). Their Al₂O₃, P₂O₅ and SiO₂ contents show negative correlations, and they thus fit the I-type granite definition. Some major and trace elements exhibit strong correlations, implying extensive fractional crystallization (e.g., hornblende and ilmenite) during the magma evolution. Two granites show enrichment in light rare earth elements and large ion lithophile elements, and depletion in high field strength elements. They have low Mg^# values (38.7–17.3) and Y/Nb ratios (0.45–0.16), and yield dominantly negative ε_Hf(t) values (1.4–−13.9), indicating a heterogeneous source and their derivation from remelting of ancient continental crust (e.g., Mesoproterozoic Liwu Group in this region) with minor juvenile crust. Combined with prior studies, we conclude that the Wenjiaping and Wulaxi granites were formed in a post-collisional extensional regime, and were responsible for the 163.7–151.1 Ma magmatic hydrothermal Cu-W mineralization in the Jianglang dome. In addition, two granite plutons intrude this dome and they are undeformed, implying that the doming was during the Early to Middle Jurassic.  相似文献   

内蒙古苏左旗北部晚二叠世花岗岩地球化学特征及意义          下载免费PDF全文

陈军林  何雨栗  杨国林  孙柏年  刘珂男 《高校地质学报》2014,20(1):68-80

苏尼特左旗北部晚二叠世花岗岩分布在索伦缝合带北侧,地处西伯利亚板块东南缘古生代陆壳增生区,对这些花岗 岩的研究有助于加深对内蒙古中部地区晚古生代构造演化的认识。主微量元素地球化学特征分析结果显示:苏尼特左旗北 部晚二叠世花岗岩总体呈富硅、富碱、相对富钠贫钾、贫钙镁的特征,属高钾钙碱性系列。富集 LREE 和 LILE,具明显的 铕负异常;微量元素相对亏损 Nb,Ta,Sr,P,Ti,富集 Pb,Hf,Dy 等元素。成因类型为高分异的 I 型花岗岩,产于汇聚板 块边缘大陆弧环境,该结果指示索伦缝合带在晚二叠世还未封闭,西伯利亚和华北板块还未完全碰撞拼合,苏尼特左旗北 部地区在晚二叠世可能正处于由板块俯冲向碰撞造山转换的阶段  相似文献   

内蒙古乌拉特中旗乌兰地区含石榴石花岗岩锆石U-Pb年龄及地质意义   总被引：5，自引：1，他引：4  

张青伟  刘正宏  柴社立  徐仲元  徐学纯 《吉林大学学报(地球科学版)》2011,41(3):745-752

对乌拉特中旗乌兰地区含石榴石花岗岩进行了同位素地质年代学和岩石地球化学研究,探讨了其形成时代和构造背景。利用锆石SHRIMP U-Pb法测得含石榴石花岗岩岩体的年龄为（256.4±2.2） Ma,表明其形成于晚二叠世;岩石地球化学特征显示属弱过铝质I型花岗岩,物源主要为上陆壳硬砂岩,形成于后碰撞构造环境,源区岩浆部分熔融程度较低,可能是由I型花岗质流体与岩浆演化后期热液流体反应而分异结晶形成的。根据含石榴石花岗岩产出的大地构造位置、形成环境及侵位时代,推断研究区内华北板块北缘与西伯利亚板块南缘的碰撞缝合时间上限早于256.4 Ma。  相似文献   

内蒙古阿尔山地区成矿花岗岩形成时代及其找矿意义     

解惠  田景春  武利文  朱迎堂  吴驰华  沈坤  顾往九  张峰 《吉林大学学报(地球科学版)》2011,41(5):1432-1440

阿尔山地区是大兴安岭中南段多金属成矿带的重要地段。该区热液脉型铁锰多金属矿、热液脉型钼（铜）矿和矽卡岩型铅锌多金属矿等3种代表性矿床（点）的成矿花岗岩的形成时代一直是研究的薄弱环节。通过多种高精度的U-Pb年龄测定,区内成矿花岗岩的形成时代分别为印支早期（(237.8±2.3) Ma）和燕山中期（(152.2±2.9) Ma）、燕山晚期（(135.1±0.4) Ma）,与邻区乌兰浩特－索伦地区基本可以对应。而前人划定的海西期花岗岩,实际为燕山晚期;划定的燕山早期花岗岩,实际为印支早期、燕山中期。研究成果对于区内花岗岩浆及期后热液与多金属成矿作用在时间上的关系提供了重要依据,对确定区內相应多金属矿类型的成矿花岗岩时代亦提供了可资对比的依据。  相似文献   

新疆库地北中三叠世斑状二长花岗岩锆石U-Pb年龄、地球化学特征及其构造意义     

白春东  王金贵  李典  专少鹏  陈圆圆  张新征  张子轩 《地质通报》2019,38(5):802-809

西昆仑山是塔里木地块和羌塘地块在晚中生代碰撞造山的产物,古特提斯洋分支库尔良-阿羌裂谷闭合时限亦存在争议。以库地北斑状二长花岗岩为研究对象,进行岩石学、地球化学和年代学研究。获得LA-ICP-MS锆石U-Pb年龄244.42±0.87Ma,时代为中三叠世。斑状二长花岗岩的SiO_2含量为65.57%～67.70%,Mg~#值为35～38,A/CNK值为0.90～1.01,属于偏铝质高钾钙碱性岩石。稀土元素总量为193×10~(-6)～339×10~(-6),δEu=0.72～0.78,具弱负Eu异常。微量元素Rb、K、Th、U、La、Ce、Zr富集,Nb、Ti、P中等-强亏损。斑状二长花岗岩属于I型花岗岩,源岩为安山岩,形成于俯冲的大陆岛弧环境。结合区域资料和前人研究成果表明,斑状二长花岗岩形成于中三叠世大陆岛弧环境,中三叠世库地一带存在古特提斯洋壳俯冲活动,库尔良-阿羌裂谷尚未消减闭合。  相似文献